General fluid correlations
Gas PVT correlations
BWR
Z factor, viscosity, and other gas properties have been correlated accurately with corresponding-states principles, where the property is correlated as a function of reduced pressure and temperature.
pr = p / pc and Tr = T / Tc
In the BWR methodology, pc and Tc for gas mixtures are determined from the gas gravity from the following relationship.
The upper curve for each is used for dry gas and the lower curve for wet gas. Corrections for non-hydrocarbon components are also provided as insets in the plot.
BWR determination of Z
Correcting for Sour Gas
Compressibility
Piper Detail
Similar to the calculations detailed above, with the Piper Detail correlation gas properties are determined from the Tc and pc of the gas mixture. When using Piper Detail, the user provides a detailed composition of the gas. In this case, rather than using a tabular/graphical approach to determining Tc and pc, they can be determined directly.
Gas viscosity correlations
Gas viscosity correlations for Carr et al., Lee, Gonzalez, and Eakin, and Lucas are shown below.
Carr et al
Lee, Gonzalez, and Eakin
Lucas
Oil PVT correlations
Vasquez & Beggs
Developed from data obtained from fields all over the world and generally applicable for all oil types. Covers a wide range of pressures, temperatures and oil properties.
De Ghetto et al
These equations are suitable for oils with gravity of 10° < API < 22.3°. A modified version of the De Ghetto equations exists for oils below 10°, however this is outside the range of Piper™ intended use and the equations are not listed.
Glaso
This correlation is based on North Sea crude-oil data. It is suitable for oil gravity of 22° < API < 48° and believed to be less accurate for Rso > 1400 scf/STBO. This equation cannot be used for p > 19285 psia as a result of the pb* equation.
Hanafy et al
This correlation has been developed independent of oil gravity and temperature. Comparisons have demonstrated that it is more applicable to light oils.
Standing
Applicable for oil gravity of 16° < API < 64°
The oil compressibility in this equation is obtained from the Vasquez and Beggs correlation.
Petrosky and Farshad
Applicable for oil gravity of 16° < API < 45°. For Gulf of Mexico oils, it has been found to provide improved results over Standing, Vasquez and Beggs, and Glaso.
Velarde at al
Applicable for oil gravity of 12° < API < 55°
Solution Gas Oil Ratio for Saturated Oil
The reduced solution gas oil ratio solution below can be used to determine the actual solution gas oil ratio (Rso in the second equation) at any pressure below the bubblepoint.
This is used for a 10 step iteration process using the following equations. The 9th and 10th iterations are averaged for a final ρpo.
The oil compressibility in this equation is obtained from the Vasquez and Beggs correlation.
Oil Viscosity Correlations
Beggs and Robinson
Beggs and Robinson developed an empirical correlation for determining the viscosity of dead oil. The correlation originated from analyzing 460 dead oil viscosity measurements. The data set from which the results were obtained ranged from 16°API to 58°API and 70°F to 295°F. The correlation tends to overstate the viscosity of the crude oil when dealing in temperature ranges below 100°F to 150°F.
De Ghetto et al
All correlations listed are applicable to oil gravity of 10° < API < 22.3°. De Ghetto has also developed correlations applicable to oil gravity below 10°, however this is outside the intended use of Piper and these correlations are not listed.
Hanafy et al
Observations have demonstrated that this correlation is most appropriate for light oils.
Khan et al